Brass Vs Steel 7,9mm cartridges
The major reason the Ground troops on the Russian Front scrounged Luftwaffe brass 7,9 ammo was that it was more reliable at low temperature than steel cased ammo.
The reasons for this are as follows: Ammo for High altiturde Aircraft use must have 100% primer reliability (Synchronised Guns) and Low temperature stability ( ie, at high altitude, even in the tropics, the air temperature ios similar to a Russian Winter on the ground.
Primers are affected by very low temperatures.
Secondly, steel case technology still had extractability issues with extractability in 1941-44, due to cases "rebound" (or lack of it) and lacquer fouling problems...Brass did not have this problem, at either normal summer temperatures or at Russian Winter temps.
Thirdly, even though loaded to the same ballistic characteristics, Luftwaffe Cartridges were, more often than not, loaded with progressive burning Tubular grain Powder, as opposed to Ground cartridges (Army) which were mostly loaded ( almost all) with "Blattchen" Powder(Flake) giving different pressure-wave characteristics.
All these features were of little importance to the German MG gunner, who wanted only for his piece to work reliably in a winter where even touching bare metal with bare skin left the skin welded(frozen) to the metal, and where gunners slept with their guns under the same blankets to keep them "workable".
Regards,
Doc AV
AV Ballistics.