The difference in shoulder angle is of NO Practical Significance in the chambering and firing of ammunition. The Cartridge will fit both chambers, and fire safely...it is called Cartridge-to-Chamber tolerances.
And unless you are fitting a new chambered barrel ( ie, newly made up after-market), Headspacing is a waste of time with Milsurps.
Doc AV
I have tested over 25 Mosin Nagant M91 and 91/30 rifles, so as to be safe, not sorry.
Then, too, I have Enfields, Mausers... all tested for headspace... Thank you very much, military training!
Two of the Mosin Nagants had excessive head space, though they appeared "newly refurbed".
A third one would not chamber a milsurp cartridge. The bolt head was 0.010" too long, but, when swapped with one of the two with excess space, both tested GO! I have 4 spare bolts, and pulled the bolt head for the other one with excessive head space, so all worked out great!
I make certain the chamber (and the locking lugs in the receiver) are clean of any cosmoline or goo...
I sometimes wonder if, in the heat of the war (these are all 1943 built refurbs) someone new to the line could have made a mistake, or not measured, or, if there were some saboteurs...
My Argentine 1891 Mauser? Yep, am figuring out all the safe parts and specs on her, too. Then, we'll shoot paper, and pigs...