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You could pull the rounds and reuse the powder in a proper rifle casing without a problem....that has been done. 'Machining' brass cases does not sound like a good idea and def not time worthy.
As Ed noted they are corrosive but if you change out the brass to PPU/Norma and use new primers then they will not be corrosive. The bullets and powder loads have been used in new brass by others (some vids on that) with no issues.
 
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